3rd International Conference on Applied Crystallography
Atlanta, USA
Maryam Kiani
Sichuan University, China
Title: Facile synthesis of Ni-doped ZnFe2O4 nanoparticles supported on carbon black as efficient electrocatalyst for oxygen reduction reaction in fuel cells
Biography
Biography: Maryam Kiani
Abstract
Novel nanocomposite system Ni-doped ZnFe2O4 with carbon black was efficiently synthesized for oxygen reduction reaction (ORR) by a simple, scalable hydrothermal synthesis route. Face Centered Cubic (FCC) phase of the Ni-doped ZnFe2O4 nanocomposite was confirmed by X-Ray Powder Diffraction (XRD) analysis. The average particle size is calculated at 20nm. The as-synthesized Ni-doped ZnFe2O4/C nanocomposite displays enhanced ORR catalytic performance than pure ZnFe2O4, ZnFe2O4/C, and Ni-doped ZnFe2O4/C, which mostly favors a desired direct 4e- reaction pathway in the ORR. The improved electrocatalytic performance of the Ni-doped ZnFe2O4/C nanocomposite is ascribed to the doping of Ni atoms in zinc ferrite with carbon black, which affects the lattice parameter of crystal structure, particle size, and specific surface area and the strong coupling of with carbon black.